Amines and Diazonium Salts (Comp. containing Nitrogen)

Amines and Diazonium Salts (Comp. containing Nitrogen) logoSubject: Chemistry    Exam: AIEEE

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Important Concepts in Amines and Diazonium Salts (Comp. containing Nitrogen)

Find notes, videos, important points and questions to practice on each of these concepts.

  • Methods of Preparation - Amines

  • Aliphatic Amines

  • Aromatic Amines

  • Cyanides and Isocyanides

  • Nitro Compounds

  • Amides (Diazonium Salts)

  • Hoffmann Elimination

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Important Points

Methods of preparation of Amines are: Reduction of nitro compounds , reaction of halides with ammonia , Hofmann degradation of amides , reduction of nitriles and amides.
Test for primary Amine (Carbylamines reaction) the treatment of a primary amine with chloroform and alcoholic potash produces carbylamines (isocyanides) which has most offensive smell. This test is not exhibited by secondary and tertiary amines.
In gaseous phase , the order of basicity is R3N >R2NH > RNH2 > NH3
Test for Secondary Amine is Liebermann reaction

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