Concept Superstars

Tusshar Sharma
Highest scorer for 2 tests.
Ask Tusshar Sharma to answer this question.
Posted on : 01:31:36 PM on November 11, 2009
which is easier : abstraction of H or D
which is easier : abstraction of H or D
you can answer on the basis of dissociation enthalpy
Hide
Answers :
![]() | Posted on : 12:57:35 PM on November 24, 2009 The abstraction of deuterium (D) by hydrogen (H) atoms (respectively H
by D) on both perfectly crystalline and ion bombarded graphite
surfaces using high resolution electron energy loss spectroscopy. On
an initially defect free graphite surface, abstraction of D by H
(reciprocally and reversibly H by D) is a quite efficient process at
room temperature. Measurements demonstrate that the abstraction occurs
almost essentially with the adsorbed atoms on “weakly” reactive
sites. Reciprocally, atoms adsorbed on defects with sp3 configuration
participate in a much lower extent to the abstraction mechanism.
Obviously, this phenomenon always occurs when exposing a surface to an
atomic hydrogen beam and illustrates the competition between sticking
and molecules formation by abstraction. So i think abstraction of H is more easier than D |
» Pending Questions
a 3:2 molar mixture of N2 and CO is present in avessel of500...
By:aisha khan at 09:44:52 PM on November 14, 2011
By:aisha khan at 09:44:52 PM on November 14, 2011
» Popular Questions


Improvement Plan



Offline

